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The short answer:
Plunging works by using water pressure to force the clog through the pipe. Air is compressible, but water is not. If your toilet bowl is mostly empty, you are just pumping air, which won't generate enough force to move the blockage. why isn't my plunger working
This is intended for flat surfaces like sinks and bathtubs. It struggles with toilets because it cannot create a secure, airtight seal against the curved bottom of a toilet bowl. The short answer: Plunging works by using water